The effect of gas-phase chemistry on aqueous-phase sulfur dioxide oxidation rates     

William R. Stockwell 《Journal of Atmospheric Chemistry》1994,19(3):317-329

The rates and mechanisms of both gas and liquid phase reactions for the oxidation of sulfur dioxide play an important role in the production of atmospheric acids and aerosol particles. Rhodeet al. (1981) concluded that sulfate production rates were highly non-linear functions of sulfur dioxide emission rates. Their modelling study used an HO _x termination mechanism for the HO—SO₂ reaction in the gas-phase. Stockwell and Calvert (1983) determined that one of the products of the overall reaction of HO with sulfur dioxide was an HO₂ radical. The National Research Council (1983) using a version of the Rhodeet al. (1981) model modified to include HO₂ production from the HO—SO₂ reaction concluded that sulfate production becomes much more linear with respect to reductions in sulfur dioxide emissions. However, the cause of this increased linearity was not explained by the National Research Council report. It is demonstrated that the increased linearity is due to the coupling of gas-phases and aqueous phase chemistry. The gas-phase sulfur dioxide oxidation mechanism has a very significant effect on hydrogen perodide production rates.  相似文献   

厦门酸雨与气象要素的关系及污染源的分析   总被引：1，自引：0，他引：1  

俞绍才  蔡小平  陈小江  陈泽面 《气象》1994,20(5):20-23

根据厦门市１９８３－１９９１年９年春雨，梅雨及台风雨酸度的观测结果，结合各场雨水同步观测的气象要素资料，分析各类型雨水酸度与气象要素的关系。同时依降水的酸化原理估计了外来源及局的地源对厦门酸雨形成的贡献。  相似文献   

Structural relationships between a brown coal and its kerogen and humic acid fractions     

T.V. Verheyen  A.G. Pandolfo  R.B. Johns 《Organic Geochemistry》1985,8(5):375-388

A South Australian Tertiary brown coal is fractionated into humic acid and kerogen fractions. These related samples are then subjected to a number of different analytical techniques including infrared and¹³C-Nuclear Magnetic Resonance spectroscopies and pertrifluoroacetic acid oxidation. Structural conclusions are drawn from an integrated consideration of the data. Brown coal aliphatic structure is concentrated in the kerogen and the solvent soluble polar acid fractions. The humic acids are the most aromatic and contain a high degree of hydrogen bonding. Only very minor amounts of long polymethylene chain structures are observed in the humic acids, in complete contrast to the kerogen fraction. Different organic detrital origins are proposed for the coal fractions.  相似文献   

The importance of atmospheric input of terrestrial organic material to deep sea sediments     

Robert B. Gagosian  Edward T. Peltzer 《Organic Geochemistry》1986,10(4-6)

The concentrations of lipids were determined in atmospheric particle, gas and rain samples collected from the tropical North Pacific to assess lipid sources, transport mechanisms and fluxes to the ocean surface. Four lipid compound classes (aliphatic hydrocarbons, fatty alcohols, fatty acid esters, and salts) all unequivocally show a terrestrial vascular plant source. These aerosol lipids originate from wind erosion of Asian and American soils and direct emission from vegetation. The major fluxes result from rain rather than dry deposition. These fluxes are large enough to have a major potential impact on the inventory of terrestrially derived lipid material found in deep-sea sediments. This has been showm for n-alkanes, fatty alcohols, fatty acids, total lipids and for organic carbon. By comparing atmospheric and sediment trap fluxes with sediment accumulation rates, it is suggested that some biogenic terrestrial material is more protected from degradation than marine-derived material.  相似文献   

长春市深部地下水赋存规律之我见     

李端生 《吉林地质》1995,14(4):63-68

长春市北西或北北西向扭性断裂或断裂带是客观存在，它对长春市深部地下水循环与循存起控制作用，是深部基岩裂隙水的主要导水通道，且大都为富水带。原北东向压扭性断裂或断裂带起阻水作用，二者相得益彰。笔者于长春北郊贫水区，利用这一新理论，在水文地质调查基础上，结合多种水文物探手段布孔凿井，打出一口水量丰富的优质矿泉水井，进而验证了北西向富水说，了箕市深部地下水赋存规律的新认识，此说不但对长春市供水有实际意义  相似文献   

FTIR studies of reactions between the nitrate radical and haloethenes     

I. M. W. Noremsaune  J. Hjorth  C. J. Nielsen 《Journal of Atmospheric Chemistry》1995,21(3):223-250

Products and mechanisms for the gas-phase reactions of NO₃ radicals with CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂,cis-CHCl=CHCl andtrans-CHCl=CHCl in air have been studied. The experiments were carried out at 295±2 K and 740±5 Torr in a 480-L Teflon-coated reaction chamber and at 295±2 K and 760±5 Torr in a 250-L stainless steel reactor. NO₃ was generated by the thermal dissociation of N₂O₅. Experiments with¹⁵NO₃ and CD₂CDCl have also been performed. The initially formed nitrate peroxynitrates decay into carbonyl compounds, nitrates, HCl and ClNO₂. In adidtion, there are indications of nitrooxy acid chlorides being produced. The reactions with CH₂=CCl₂ and CHCl=CCl₂ are more complex due to release of chlorine atoms which eventually lead to formation of chloroacid chlorides.A general reaction mechanism is proposed and the observed concentration-time profiles of reactants and products are simulated for each compound. The rate constants for the initial step of NO₃ addition to the chloroethenes are determined as: (2.6±0.5, 9.4±0.9, 2.0±0.4 and 1.4±0.4) × 10^–16 cm³ molecule^–1 s^–1 for CH₂=CHCl, CH₂=CCl₂, CHCl=CCl₂ andcis-CHCl=CHCl, respectively.  相似文献   

云南临沧地区帮卖盆地含铀煤中锗矿的研究   总被引：8，自引：0，他引：8  

张淑苓  王淑英  尹金双 《铀矿地质》1987,(5)

帮卖盆地是一个不对称山间向斜盆地,其基底为海西·燕山期(γ~3_4-γ~2_5)花岗岩体。盖层为新第三纪的含煤碎屑岩。锗矿体大部分存在于N_1~2煤层中。含铀煤主要为变质程度低的褐煤,属于半暗-半亮煤、暗亮煤及亮暗煤。锗在煤中的存在形式:1.主要为腐植酸锗络合物及锗的有机化合物;2.一部分呈吸附状态;3.极少数呈类质同象。  相似文献   

桉树腐殖酸(HA)专用肥区域试验与配方的优选     

钱国钦 《福建地理》2007,(4)

采用随机区组设计,以等价投入的常规化肥为对照,开展专用肥多点施肥试验研究.通过专用肥对林木生长量、林相特征的影响分析,结果表明:与等价投入(肥料成本)的常规化肥相比,施用系列专用肥的林分生长量均显著或极显著地高于常规化肥处理,且叶片浓绿、树势强壮,施后19个月内,树高、胸径、材积分别提高了7.8%~51.8%、9.8%~53.0%和30%以上,叶片叶绿素含量提高26.3%~94.2%,叶面积指数提高41.0%~172.8%.经对HA桉树专用肥的增产性、适应性和稳定性的综合分析与评定,选出基肥专用的优化配方为:有机质≥30.0%、N P2O5 K2O≥6.0%(2.5-2.0-1.5)、腐殖酸总量≥8.0%,并加上适量的"绿滴"复合微生物菌剂(于施用时和基肥按每50 kg∶1 kg的量掺入);追肥专用的优化配方为:有机质≥20.0%、N P2O5 K2O≥20.0%(9-8-3)、腐殖酸总量≥6.0%.  相似文献   

Simulation of the dissolution of weathered versus unweathered limestone in carbonic acid solutions of varying strength     

M. J. Thornbush  H. A. Viles 《地球表面变化过程与地形》2007,32(6):841-852

A simulation was undertaken within a climatic chamber to investigate limestone dissolution under varied carbonic acid (H₂CO₃) strengths as a possible analogue for future increases in atmospheric CO₂ arising from global warming. Twenty‐eight samples cut from a block of Bath (Box Hill) limestone from Somerville College, Oxford, which had been removed during restoration after 150 years in an urban environment, were weighed and placed in closed bottles of thin plastic containing varying concentrations of H₂CO₃. Half of the stone samples were derived from exposed surfaces of the stone block (weathered) while the others were obtained from the centre of the block on unexposed surfaces (unweathered). The purpose of this was to compare dissolution of previously weathered versus unweathered surfaces in strong (pH 4·73) versus weak (pH 6·43) solutions of H₂CO₃. A temperature of c. 19 °C was maintained within the chamber representing a plausible future temperature in Oxford for the year 2200 given current warming scenarios. The simulation lasted 25 days with a few stone samples being removed midway. Stone samples show reduced weight in all cases but one. There was greater dissolution of stone samples in a strong H₂CO₃ solution as conveyed by higher concentrations of total hardness and Ca²⁺ in the water samples as well as enhanced microscopic dissolution features identified using SEM. The simulation confirms that enhanced atmospheric CO₂ under global warming, given adequate moisture, will accelerate dissolution rates particularly of newly replaced limestone building stones. However, previously weathered surfaces, such as those on historical stone exposed for a century or more, appear to be less susceptible to the effects of such increased rainfall acidity. Conservation techniques which remove weathered surfaces, such as stone cleaning, may accelerate future decay of historical limestone structures by increasing their susceptibility to dissolution. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

陕西省山阳县小河口地区酸性-中酸性岩体地质特征及其成矿地质条件分析   总被引：11，自引：0，他引：11  

张银龙 《陕西地质》2002,20(2):27-38

通过对山阳地区地层、构造、岩浆岩特征的论述 ,归纳总结了区内酸性—中酸性小岩体的空间分布、岩石类型、岩石主要矿物、岩石化学成分、岩石碱度、稀土元素、微量元素等特征 ,从五个方面提出了酸性—中酸性小岩体具有壳幔同熔成因的证据 ,分析总结了山阳小河口地区以酸性—中酸性小岩体成矿作用为主的多金属成矿规律 ,提出了成矿模式。  相似文献